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This is the Monument to the Martyrs of 1809, at Garriga i Bachs Square in the Gothic Quarter (Barri Gotic) of Barcelona. It honors the memory of men executed during Napoleonic occupation (see Napoleonic Wars). The bronze sculpture was made by Josep Llimona and the wall relief by Vicenç Navarro in 1941.
PS: By the way I hope FC Barcelona players don't look as dead and cold as these statues when they visit Liverpool tonight to stay in the Champions League tournament.